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Ok, that's insane (except for the water)
Gem said:
http://sparklerredpanda.tumblr.com/post/173889514685/tsuyu-vs-toga-step-by-step He posted a breakdown of his work on this here, really fanstastic stuff
Thank you so much for the link. It's incredible how he explained his process in so much depth. Not common.
I saw this before on Tumblr, according to the hashtags, it was made in TVPaint.